NIMTE OpenIR  > 2018专题
Microwave-assisted synthesis of well-shaped UiO-66-NH2 with high CO2 adsorption capacity
Huang, Aisheng; Wan, Linlin; Caro, Juergen
2018
发表期刊MATERIALS RESEARCH BULLETIN
卷号98页码:308-313
摘要In a detailed study, the influence of microwave irradiation, synthesis time and temperature, addition of acetic acid (HAc) as a modulator on the morphology, crystallinity and stability of UiO-66-NH2 is investigated to develop a reliable and reproducible strategy for the preparation of well-shaped UiO-66-NH2. The UiO-66-NH2 were characterized by powder X-ray diffraction (PXRD), field emission scanning electron microscopy (FESEM), thermogravimetric analysis (TGA), and gas adsorption. It is found that well-shaped UiO-66-NH2 with a high CO2 adsorption capacity can be synthesized in a short time by microwave heating. The UiO-66-NH2 crystals synthesized by microwave heating are of high quality and show a superior CO2 adsorption capacity (5.8 mmol/g at 273k and 1 bar) due to the strong interactions between the -NH2 group and CO2. The CO2/N-2 selectivity of the obtained UiO-66-NH2 at 298 K and 1 bar is 66, which is much higher than that of the pristine UiO-66 of 17.8.
关键词Metal-organic Frameworks Mixed-matrix Membranes Carbon-dioxide Modulated Synthesis Scale-up Capture Stability Water Mof
学科领域Materials Science
语种英语
文献类型期刊论文
条目标识符http://ir.nimte.ac.cn/handle/174433/16847
专题2018专题
推荐引用方式
GB/T 7714
Huang, Aisheng,Wan, Linlin,Caro, Juergen. Microwave-assisted synthesis of well-shaped UiO-66-NH2 with high CO2 adsorption capacity[J]. MATERIALS RESEARCH BULLETIN,2018,98:308-313.
APA Huang, Aisheng,Wan, Linlin,&Caro, Juergen.(2018).Microwave-assisted synthesis of well-shaped UiO-66-NH2 with high CO2 adsorption capacity.MATERIALS RESEARCH BULLETIN,98,308-313.
MLA Huang, Aisheng,et al."Microwave-assisted synthesis of well-shaped UiO-66-NH2 with high CO2 adsorption capacity".MATERIALS RESEARCH BULLETIN 98(2018):308-313.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Huang, Aisheng]的文章
[Wan, Linlin]的文章
[Caro, Juergen]的文章
百度学术
百度学术中相似的文章
[Huang, Aisheng]的文章
[Wan, Linlin]的文章
[Caro, Juergen]的文章
必应学术
必应学术中相似的文章
[Huang, Aisheng]的文章
[Wan, Linlin]的文章
[Caro, Juergen]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。