NIMTE OpenIR  > 2018专题
Surface oxo-functionalized hard carbon spheres enabled superior high-rate capability and long-cycle stability for Li-ion storage
Fu, Rusheng; Chang, Zhenzhen; Shen, Chengxu; Guo, Haocheng; Huang, Heran; Xia, Yonggao; Liu, Zhaoping
2018
发表期刊ELECTROCHIMICA ACTA
卷号260页码:430-438
摘要Hard carbon is emerging as a highly promising material for power-demanded energy storage devices. Recently, introducing heteroatom such as oxygen is confirmed to be available to improve the capacity. However, it remains a significant challenge to achieve simultaneously superior high-rate capability and long-term cycling stability. Here we demonstrate that the surface oxo-funcitionalized hard carbon spheres (o-HCS, 4.2m(2) g(-1)) derived from mild oxidative approach enhance pseudocapacitance lithiumion storage with improved Li-ion diffusivity and thus exhibit high-rate capacity and long cycle life in both Li-ion batteries and Li-ion capacitors. The o-HCS electrode delivers specific capacity of around 275 mAh g(-1) at 744mA g(-1) (2C) and capacity retention of above 92.0% and about 86.5% after 1100 and 1700 cycles, respectively. Impressively, it delivers above 110mAh g(-1) at extreme high current density of 14.88 A g(-1) (40C). As well, o-HCS electrode in Li-ion capacitor shows a capacitance of 34.8 F g(-1) (corresponding to 48.5 Whkg(-1) and 3.6 kW kg(-1)) at the current density of 3720 mA g(-1), and after 7000 cycles the capacity retention is 96% (similar to 0.057% decay per cycle). (c) 2017 Elsevier Ltd. All rights reserved.
关键词High-performance Intercalation Pseudocapacitance Rechargeable Batteries Organic Electrode Energy-storage Lithium Supercapacitors Sodium Anode Nitrogen
学科领域Chemistry ; Crystallography
语种英语
文献类型期刊论文
条目标识符http://ir.nimte.ac.cn/handle/174433/16881
专题2018专题
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GB/T 7714
Fu, Rusheng,Chang, Zhenzhen,Shen, Chengxu,et al. Surface oxo-functionalized hard carbon spheres enabled superior high-rate capability and long-cycle stability for Li-ion storage[J]. ELECTROCHIMICA ACTA,2018,260:430-438.
APA Fu, Rusheng.,Chang, Zhenzhen.,Shen, Chengxu.,Guo, Haocheng.,Huang, Heran.,...&Liu, Zhaoping.(2018).Surface oxo-functionalized hard carbon spheres enabled superior high-rate capability and long-cycle stability for Li-ion storage.ELECTROCHIMICA ACTA,260,430-438.
MLA Fu, Rusheng,et al."Surface oxo-functionalized hard carbon spheres enabled superior high-rate capability and long-cycle stability for Li-ion storage".ELECTROCHIMICA ACTA 260(2018):430-438.
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