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Characterization of the Outer Layer Nanostructure in the Electrochemical Response of Stainless Steel in Aqueous Sodium Hydroxide
Man, Cheng; Dong, Chaofang; Cui, Zhongyu; Xiao, Kui; Yu, Qiang; Li, Xiaogang
2018
发表期刊ANALYTICAL LETTERS
卷号51期号:9页码:1384-1399
摘要The outer layer nanostructure of stainless steel's passive film in 0.1M NaOH has been studied by electrochemical atomic force microscopy and the role of the outer layer in the electrochemical response of stainless steel has been characterized. The outer layer is mainly composed of nanoscale particles whose average diameter is up to 13.14 +/- 3.52nm at the end of the formation period. The formation process is characterized by the nucleation, growth, and contact of oxide particles. Based on the study on the outer layer nanostructure, the gaps/boundaries between particles in the outer layer should be diffusion paths for ions across the layer. The electrochemical impedance spectroscopy analysis revealed that the ion diffusion resistance first increased and then remained stable due to the three-dimensional growth of nanoscale particles.
关键词Passive Film Alkaline-solutions Different Ph Behavior Growth Iron Spectroscopy Morphology Nanoscale Surface
学科领域Polymer Science
语种英语
文献类型期刊论文
条目标识符http://ir.nimte.ac.cn/handle/174433/16914
专题2018专题
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GB/T 7714
Man, Cheng,Dong, Chaofang,Cui, Zhongyu,et al. Characterization of the Outer Layer Nanostructure in the Electrochemical Response of Stainless Steel in Aqueous Sodium Hydroxide[J]. ANALYTICAL LETTERS,2018,51(9):1384-1399.
APA Man, Cheng,Dong, Chaofang,Cui, Zhongyu,Xiao, Kui,Yu, Qiang,&Li, Xiaogang.(2018).Characterization of the Outer Layer Nanostructure in the Electrochemical Response of Stainless Steel in Aqueous Sodium Hydroxide.ANALYTICAL LETTERS,51(9),1384-1399.
MLA Man, Cheng,et al."Characterization of the Outer Layer Nanostructure in the Electrochemical Response of Stainless Steel in Aqueous Sodium Hydroxide".ANALYTICAL LETTERS 51.9(2018):1384-1399.
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