NIMTE OpenIR  > 2018专题
Metal-Organic Framework Anchored with a Lewis Pair as a New Paradigm for Catalysis
Niu, Zheng; Gunatilleke, Wilarachchige D. C. Bhagya; Sun, Qi; Lan, Pui Ching; Perman, Jason; Ma, Jian-Gong; Cheng, Yuchuan; Aguila, Briana; Ma, Shengqian
2018
Source PublicationCHEM
Volume4Issue:11Pages:2587-2599
AbstractLewis pair (LP) chemistry has shown broad applications in the catalysis field. However, one significant challenge has been recognized as the instability for most homogeneous LP catalysts upon recycling, thus inevitably leading to dramatic loss in catalytic activity. Additionally, current heterogeneous LP catalysts suffer from low surface area, which largely limits their catalytic efficiency, thereby restricting their potential applications. In this work, we report the successful introduction of LPs, classical and frustrated, into a metal-organic framework (MOF) that features high surface and ordered pore structure via a stepwise anchoring strategy. Not only can the LP be stabilized by the strong coordination interaction between the LP and MOF, but the resultant MOF-LP also demonstrates excellent catalysis performance with interesting size and steric selectivity. Given the broad applicability of LPs, our work therefore paves a way for advancing MOF-LP as a new paradigm for catalysis.
KeywordAcid-base Pairs Hydrogenation Reactions Oxygen Evolution Co2 Encapsulation Conversion Alkenes Transformations Polymerization Hydroboration
Subject AreaChemistry ; Materials Science
Language英语
Document Type期刊论文
Identifierhttp://ir.nimte.ac.cn/handle/174433/17030
Collection2018专题
Recommended Citation
GB/T 7714
Niu, Zheng,Gunatilleke, Wilarachchige D. C. Bhagya,Sun, Qi,et al. Metal-Organic Framework Anchored with a Lewis Pair as a New Paradigm for Catalysis[J]. CHEM,2018,4(11):2587-2599.
APA Niu, Zheng.,Gunatilleke, Wilarachchige D. C. Bhagya.,Sun, Qi.,Lan, Pui Ching.,Perman, Jason.,...&Ma, Shengqian.(2018).Metal-Organic Framework Anchored with a Lewis Pair as a New Paradigm for Catalysis.CHEM,4(11),2587-2599.
MLA Niu, Zheng,et al."Metal-Organic Framework Anchored with a Lewis Pair as a New Paradigm for Catalysis".CHEM 4.11(2018):2587-2599.
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