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Metal-Organic Framework Anchored with a Lewis Pair as a New Paradigm for Catalysis
Niu, Zheng; Gunatilleke, Wilarachchige D. C. Bhagya; Sun, Qi; Lan, Pui Ching; Perman, Jason; Ma, Jian-Gong; Cheng, Yuchuan; Aguila, Briana; Ma, Shengqian
2018
发表期刊CHEM
卷号4期号:11页码:2587-2599
摘要Lewis pair (LP) chemistry has shown broad applications in the catalysis field. However, one significant challenge has been recognized as the instability for most homogeneous LP catalysts upon recycling, thus inevitably leading to dramatic loss in catalytic activity. Additionally, current heterogeneous LP catalysts suffer from low surface area, which largely limits their catalytic efficiency, thereby restricting their potential applications. In this work, we report the successful introduction of LPs, classical and frustrated, into a metal-organic framework (MOF) that features high surface and ordered pore structure via a stepwise anchoring strategy. Not only can the LP be stabilized by the strong coordination interaction between the LP and MOF, but the resultant MOF-LP also demonstrates excellent catalysis performance with interesting size and steric selectivity. Given the broad applicability of LPs, our work therefore paves a way for advancing MOF-LP as a new paradigm for catalysis.
关键词Acid-base Pairs Hydrogenation Reactions Oxygen Evolution Co2 Encapsulation Conversion Alkenes Transformations Polymerization Hydroboration
学科领域Chemistry ; Materials Science
语种英语
文献类型期刊论文
条目标识符http://ir.nimte.ac.cn/handle/174433/17030
专题2018专题
推荐引用方式
GB/T 7714
Niu, Zheng,Gunatilleke, Wilarachchige D. C. Bhagya,Sun, Qi,et al. Metal-Organic Framework Anchored with a Lewis Pair as a New Paradigm for Catalysis[J]. CHEM,2018,4(11):2587-2599.
APA Niu, Zheng.,Gunatilleke, Wilarachchige D. C. Bhagya.,Sun, Qi.,Lan, Pui Ching.,Perman, Jason.,...&Ma, Shengqian.(2018).Metal-Organic Framework Anchored with a Lewis Pair as a New Paradigm for Catalysis.CHEM,4(11),2587-2599.
MLA Niu, Zheng,et al."Metal-Organic Framework Anchored with a Lewis Pair as a New Paradigm for Catalysis".CHEM 4.11(2018):2587-2599.
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