NIMTE OpenIR  > 2018专题
pH and Temperature Dual-Responsive Plasmonic Switches of Gold Nanoparticle Monolayer Film for Multiple Anticounterfeiting
Liu, Baoqing; Lu, Xuefei; Qiao, Ze; Song, Liping; Cheng, Qian; Zhang, Jiawei; Zhang, Afang; Huang, Youju; Chen, Tao
2018
发表期刊LANGMUIR
卷号34期号:43页码:13047-13056
摘要Two-dimensional (2D) gold nanoparticle (Au NP) mono layer film possesses a lot of fascinating peculiarities, and has shown promising applications in photoelectrical devices, catalysis, spectroscopy, sensors, and anticounterfeiting. Because of the localized surface plasmon resonance (LSPR) property predetermined by the natural structure of metal nanoparticles, it is usually difficult to realize the reversible LSPR transition of 2D film. In this work, we report on the fabrication of a large-area freestanding Au NP monolayer film with dual-responsive switchable plasmonic property using a pH- or thermal-responsive dendronized copolymer as a stimuli-sensitive linker. In this system, an oligoethylene-glycol-based (OEG-based) dendronized copolymer (named PG1A) with pH or temperature sensitivity was first modified onto the surface of a Au NP. Then, polyethylene glycol dibenzyl aldehyde (PEG-DA) was introduced to interact with the amino moieties from PG1A before the process of oil water interfacial self-assembly of NPs, resulting in an elastic, robust, pH- or temperature-sensitive interpenetrating network among Au NPs in monolayer films. In addition, the film could exhibit reversibly plasmonic shifts of about 77 nm and inherent color changes through varying temperature or pH. The obtained free-standing monolayer film also shows an excellent transferable property, which can be easily transferred onto substrates such as plastic molds, PDMS, copper grids, and silicon wafers. In virtue of these peculiarities of the free-standing property, special plasmonic signal, and homologous macroscopic color, the transferred film was primely applied to an anticounterfeiting security label with clear color change at the designed spots, providing a new avenue to plasmonic nanodevices with various applications.
关键词Polymer Interfaces Chemistry Nanoplasmonics Nanostructures Nanomaterials Nanospheres Generation Nanosheets Resonance
学科领域Materials Science ; Physics
语种英语
文献类型期刊论文
条目标识符http://ir.nimte.ac.cn/handle/174433/17102
专题2018专题
推荐引用方式
GB/T 7714
Liu, Baoqing,Lu, Xuefei,Qiao, Ze,et al. pH and Temperature Dual-Responsive Plasmonic Switches of Gold Nanoparticle Monolayer Film for Multiple Anticounterfeiting[J]. LANGMUIR,2018,34(43):13047-13056.
APA Liu, Baoqing.,Lu, Xuefei.,Qiao, Ze.,Song, Liping.,Cheng, Qian.,...&Chen, Tao.(2018).pH and Temperature Dual-Responsive Plasmonic Switches of Gold Nanoparticle Monolayer Film for Multiple Anticounterfeiting.LANGMUIR,34(43),13047-13056.
MLA Liu, Baoqing,et al."pH and Temperature Dual-Responsive Plasmonic Switches of Gold Nanoparticle Monolayer Film for Multiple Anticounterfeiting".LANGMUIR 34.43(2018):13047-13056.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Liu, Baoqing]的文章
[Lu, Xuefei]的文章
[Qiao, Ze]的文章
百度学术
百度学术中相似的文章
[Liu, Baoqing]的文章
[Lu, Xuefei]的文章
[Qiao, Ze]的文章
必应学术
必应学术中相似的文章
[Liu, Baoqing]的文章
[Lu, Xuefei]的文章
[Qiao, Ze]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。