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Superhydrophobic oligoaniline-containing electroactive silica coating as pre-process coating for corrosion protection of carbon steel
Ye, Yuwei; Liu, Zhiyong; Liu, Wei; Zhang, Dawei; Zhao, Haichao; Wang, Liping; Li, Xiaogang
2018
发表期刊CHEMICAL ENGINEERING JOURNAL
卷号348页码:940-951
摘要This paper provided a novel coating system for Q235 steel using electrodeposited oligoaniline modified silica coating (E-M-SiO2) as a pre-process coating, which was prepared by one step coelectrodeposition of a mixture of tetraethyl orthosilicate (TEOS) and N,N'-Bis(4'-(3-triethoxysilylpropylureido)-phenyl)-1,4-quinonenediimine (TSUPQD). Microstructure, contact angle, electroactivity and anticorrosion performance were investigated by FTIR, UV-vis, AFM, SEM, OCA20 contact angle analyzer, CV and CHI-660E electrochemical workstation. The CA test indicated, in comparison with pure silica and sol-gel modified silica hybrid coatings, the electrodeposited modified silica coating exhibited a super hydrophobic performance. The CV test illustrated that the special redox property of aniline trimer was maintained in these modified silica hybrid coatings. More importantly, the anticorrosion effectiveness for Q235 steel in 3.5% NaCl solution was improved by the addition of oligoaniline modified silica as the pre-process coating. By comparison, it turned out that the epoxy/E-M-SiO2 coating system presented the lowest i(corr) value and the highest vertical bar Z vertical bar(0.01Hz) value. The corrosion protection mechanism was the synergistic effect of super hydrophobic nature of E-M-SiO2 pre-process coating and special catalytic capability of aniline trimer unit, which effectively restrained the permeation of corrosion medium and induced the formation of passive films consisted of alpha-Fe2O3 and Fe3O4 on the Q235 surface.
关键词Capped Aniline Trimer Mild-steel Anticorrosion Property Atmospheric Corrosion Vibrational-spectra Aluminum-alloys Thin-films Surface Polyaniline Electrodeposition
学科领域Physics
语种英语
文献类型期刊论文
条目标识符http://ir.nimte.ac.cn/handle/174433/17201
专题2018专题
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GB/T 7714
Ye, Yuwei,Liu, Zhiyong,Liu, Wei,et al. Superhydrophobic oligoaniline-containing electroactive silica coating as pre-process coating for corrosion protection of carbon steel[J]. CHEMICAL ENGINEERING JOURNAL,2018,348:940-951.
APA Ye, Yuwei.,Liu, Zhiyong.,Liu, Wei.,Zhang, Dawei.,Zhao, Haichao.,...&Li, Xiaogang.(2018).Superhydrophobic oligoaniline-containing electroactive silica coating as pre-process coating for corrosion protection of carbon steel.CHEMICAL ENGINEERING JOURNAL,348,940-951.
MLA Ye, Yuwei,et al."Superhydrophobic oligoaniline-containing electroactive silica coating as pre-process coating for corrosion protection of carbon steel".CHEMICAL ENGINEERING JOURNAL 348(2018):940-951.
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