NIMTE OpenIR  > 2018专题
Water oxidation by a manganese-potassium cluster: Mn oxide as a kinetically dominant "true" catalyst for water oxidation
Mousazade, Younes; Mohammadi, Mohammad Reza; Chernev, Petko; Bikas, Rahman; Bagheri, Robabeh; Song, Zhenlun; Lis, Tadeusz; Dau, Holger; Najafpour, Mohammad Mahdi
2018
Source PublicationCATALYSIS SCIENCE & TECHNOLOGY
Volume8Issue:17Pages:4390-4398
AbstractNature uses an Mn cluster for water oxidation, and thus, water oxidation using Mn clusters is interesting when used in artificial water-splitting systems. An important question is whether an Mn cluster is a true catalyst for water oxidation or not. Herein, an Mn-K cluster was investigated for electrochemical water oxidation to find the true and the kinetically dominant catalyst using X-ray absorption spectroscopy, scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectroscopy, X-ray diffraction, and electrochemical methods. The experiments showed that conversion into nanosized Mn oxide occurred for the cluster, and the nanosized Mn oxides are the true catalyst for water oxidation.
KeywordOxygen-evolving Center Cerium(Iv) Ammonium-nitrate Photosystem-ii Photosynthesis Complex Evolution Photolysis Chemistry Precursor Insights
Subject AreaChemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
Language英语
Document Type期刊论文
Identifierhttp://ir.nimte.ac.cn/handle/174433/17207
Collection2018专题
Recommended Citation
GB/T 7714
Mousazade, Younes,Mohammadi, Mohammad Reza,Chernev, Petko,et al. Water oxidation by a manganese-potassium cluster: Mn oxide as a kinetically dominant "true" catalyst for water oxidation[J]. CATALYSIS SCIENCE & TECHNOLOGY,2018,8(17):4390-4398.
APA Mousazade, Younes.,Mohammadi, Mohammad Reza.,Chernev, Petko.,Bikas, Rahman.,Bagheri, Robabeh.,...&Najafpour, Mohammad Mahdi.(2018).Water oxidation by a manganese-potassium cluster: Mn oxide as a kinetically dominant "true" catalyst for water oxidation.CATALYSIS SCIENCE & TECHNOLOGY,8(17),4390-4398.
MLA Mousazade, Younes,et al."Water oxidation by a manganese-potassium cluster: Mn oxide as a kinetically dominant "true" catalyst for water oxidation".CATALYSIS SCIENCE & TECHNOLOGY 8.17(2018):4390-4398.
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