NIMTE OpenIR  > 2018专题
Two Possible Side Reaction Pathways during Furanic Etherification
Fang, Wenting; Hu, Hualei; Ma, Zhongsen; Wang, Lei; Zhang, Yajie
2018
发表期刊CATALYSTS
卷号8期号:9
摘要The revealing mechanism of side reactions is crucial for obtaining theoretical yield in industrialization when 2,5-bis(methoxymethyl)furan (BMMF) yield is above 95%. By-products catalyzed by the conventional ZSM-5 (C-ZSM-5) and hierarchical porous ZSM-5 (HP-ZSM-5) catalytic systems were different, and some key by-products were identified. Thus, possible pathways were proposed, which helps to further improve BMMF selectivity. Additionally, HP-ZSM-5 exhibited quicker reaction rate, higher BMMF yield and selectivity, and slower deactivation process. The relatively weak acidity of HP-ZSM-5 suppresses the ring-opening reaction and subsequent side reactions, and introduction of mesopores improves mass transport and slightly increases hydration of 2,5-bis(hydroxymethyl)furan (BHMF).
关键词Hierarchical Zeolites Pyrolysis Mesoporosity Deactivation Selectivity Conversion Catalyst Biomass Diesel Zsm-5
学科领域Science & Technology - Other Topics
语种英语
文献类型期刊论文
条目标识符http://ir.nimte.ac.cn/handle/174433/17213
专题2018专题
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GB/T 7714
Fang, Wenting,Hu, Hualei,Ma, Zhongsen,et al. Two Possible Side Reaction Pathways during Furanic Etherification[J]. CATALYSTS,2018,8(9).
APA Fang, Wenting,Hu, Hualei,Ma, Zhongsen,Wang, Lei,&Zhang, Yajie.(2018).Two Possible Side Reaction Pathways during Furanic Etherification.CATALYSTS,8(9).
MLA Fang, Wenting,et al."Two Possible Side Reaction Pathways during Furanic Etherification".CATALYSTS 8.9(2018).
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