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Poly(neopentyl glycol 2,5-furandicarboxylate): A Promising Hard Segment for the Development of Bio-based Thermoplastic Poly(ether-ester) Elastomer with High Performance
Chi, Dequan; Liu, Fei; Na, Haining; Chen, Jing; Hao, Chuncheng; Zhu, Jin
2018
Source PublicationACS SUSTAINABLE CHEMISTRY & ENGINEERING
Volume6Issue:8Pages:9893-9902
AbstractWith a high melting temperature and good crystallization ability, poly(neopentyl glycol 2,5-furandicarboxylate) (PNF), a polyester derived from bio-based 2,5-furandicarboxylic acid and neopentyl glycol, has been proposed and proved to be a promising hard segment for the development of novel bio-based thermoplastic poly(ether-ester) elastomer (TPEE). The resulting TPEE, namely PNF-PTMG, has high performance comparable to the petroleum-based counterpart PBT-PTMG (i.e., Hytrel, Dupont). Among all of the existing polyesters derived from bio-based 2,5-furandicarboxylic acid (FDCA), PNF has perfectly balanced properties, namely, a high melting temperature of 200 degrees C and a good crystallization ability to easily grow medium to large-size crystalline spherulites. Characterizations based on dynamic mechanical analysis and small-angle X-ray scattering suggest that there are two domains in PNF-PTMG, the crystalline PNF and a mixture of amorphous PNF and PTMG. These two domains form microphase separation induced mainly by the crystallization of PNF. By adjusting the PTMG soft segment from 30 to 60 wt%, PNF-PTMG shows a melting temperature, tensile modulus (E), and elongation at the break (epsilon(b)) ranging from 180 to 134 degrees C, 738 to 56 MPa, and 38 to 1089%, respectively. More importantly, the shape recovery ratios increase from 57 to 90% at 200% strain when the amount of PTMG increases from 50 to 70 wt%, indicating excellent elastic property. These results indicate that PNF is an excellent hard segment to serve as a strong physical cross-link so that PNF-PTMG is able to display high performance comparable to extensively commercialized PBT-PTMG.
KeywordBiobased Multiblock Copolymers Renewable Resources Poly(Trimethylene Terephthalate) Solubility Parameter Microphase Separation Aromatic Polyesters Thermal-properties Elastic Properties Block Acid
Subject AreaPhysics
Language英语
Document Type期刊论文
Identifierhttp://ir.nimte.ac.cn/handle/174433/17278
Collection2018专题
Recommended Citation
GB/T 7714
Chi, Dequan,Liu, Fei,Na, Haining,et al. Poly(neopentyl glycol 2,5-furandicarboxylate): A Promising Hard Segment for the Development of Bio-based Thermoplastic Poly(ether-ester) Elastomer with High Performance[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2018,6(8):9893-9902.
APA Chi, Dequan,Liu, Fei,Na, Haining,Chen, Jing,Hao, Chuncheng,&Zhu, Jin.(2018).Poly(neopentyl glycol 2,5-furandicarboxylate): A Promising Hard Segment for the Development of Bio-based Thermoplastic Poly(ether-ester) Elastomer with High Performance.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,6(8),9893-9902.
MLA Chi, Dequan,et al."Poly(neopentyl glycol 2,5-furandicarboxylate): A Promising Hard Segment for the Development of Bio-based Thermoplastic Poly(ether-ester) Elastomer with High Performance".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 6.8(2018):9893-9902.
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