NIMTE OpenIR  > 2018专题
New formulation for reduction potentials of (Cu, Ni, Al, Zn)-lanthanide alloys - Implications for electrolysis-based pyroprocessing of spent nuclear fuel
Zhang, Milin; Wang, Pu; Zhang, Yiming; Ji, Debin; Yan, Yongde; Shi, Weiqun; Huang, Qing; Du, Shiyu
2018
Source PublicationELECTROCHEMISTRY COMMUNICATIONS
Volume93Pages:180-182
AbstractIn this work, the electrochemical behavior of lanthanides (except promethium) on several active cathodes in LiCl-KCl molten salts was investigated. We have discovered that the reduction potentials of lanthanide alloys present a "bimodal effect". A numerical model was established based on the result of multiple linear regression analyses, which indicates that the reduction potentials are correlated with differences in atomic radii and differences in electronegativity. Employing the fitted formulae, which provide a preliminary model of the behavior of these elements in electrolysis-based pyroprocessing, the electrochemistry of both lanthanides and actinides on active metal cathodes could be reasonably estimated.
KeywordMolten-salt Electronegativity Electrodes Energy
Subject AreaPolymer Science
Language英语
Document Type期刊论文
Identifierhttp://ir.nimte.ac.cn/handle/174433/17284
Collection2018专题
Recommended Citation
GB/T 7714
Zhang, Milin,Wang, Pu,Zhang, Yiming,et al. New formulation for reduction potentials of (Cu, Ni, Al, Zn)-lanthanide alloys - Implications for electrolysis-based pyroprocessing of spent nuclear fuel[J]. ELECTROCHEMISTRY COMMUNICATIONS,2018,93:180-182.
APA Zhang, Milin.,Wang, Pu.,Zhang, Yiming.,Ji, Debin.,Yan, Yongde.,...&Du, Shiyu.(2018).New formulation for reduction potentials of (Cu, Ni, Al, Zn)-lanthanide alloys - Implications for electrolysis-based pyroprocessing of spent nuclear fuel.ELECTROCHEMISTRY COMMUNICATIONS,93,180-182.
MLA Zhang, Milin,et al."New formulation for reduction potentials of (Cu, Ni, Al, Zn)-lanthanide alloys - Implications for electrolysis-based pyroprocessing of spent nuclear fuel".ELECTROCHEMISTRY COMMUNICATIONS 93(2018):180-182.
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