NIMTE OpenIR  > 2018专题
New formulation for reduction potentials of (Cu, Ni, Al, Zn)-lanthanide alloys - Implications for electrolysis-based pyroprocessing of spent nuclear fuel
Zhang, Milin; Wang, Pu; Zhang, Yiming; Ji, Debin; Yan, Yongde; Shi, Weiqun; Huang, Qing; Du, Shiyu
2018
发表期刊ELECTROCHEMISTRY COMMUNICATIONS
卷号93页码:180-182
摘要In this work, the electrochemical behavior of lanthanides (except promethium) on several active cathodes in LiCl-KCl molten salts was investigated. We have discovered that the reduction potentials of lanthanide alloys present a "bimodal effect". A numerical model was established based on the result of multiple linear regression analyses, which indicates that the reduction potentials are correlated with differences in atomic radii and differences in electronegativity. Employing the fitted formulae, which provide a preliminary model of the behavior of these elements in electrolysis-based pyroprocessing, the electrochemistry of both lanthanides and actinides on active metal cathodes could be reasonably estimated.
关键词Molten-salt Electronegativity Electrodes Energy
学科领域Polymer Science
语种英语
文献类型期刊论文
条目标识符http://ir.nimte.ac.cn/handle/174433/17284
专题2018专题
推荐引用方式
GB/T 7714
Zhang, Milin,Wang, Pu,Zhang, Yiming,et al. New formulation for reduction potentials of (Cu, Ni, Al, Zn)-lanthanide alloys - Implications for electrolysis-based pyroprocessing of spent nuclear fuel[J]. ELECTROCHEMISTRY COMMUNICATIONS,2018,93:180-182.
APA Zhang, Milin.,Wang, Pu.,Zhang, Yiming.,Ji, Debin.,Yan, Yongde.,...&Du, Shiyu.(2018).New formulation for reduction potentials of (Cu, Ni, Al, Zn)-lanthanide alloys - Implications for electrolysis-based pyroprocessing of spent nuclear fuel.ELECTROCHEMISTRY COMMUNICATIONS,93,180-182.
MLA Zhang, Milin,et al."New formulation for reduction potentials of (Cu, Ni, Al, Zn)-lanthanide alloys - Implications for electrolysis-based pyroprocessing of spent nuclear fuel".ELECTROCHEMISTRY COMMUNICATIONS 93(2018):180-182.
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