NIMTE OpenIR  > 2018专题
Barrier mechanism of multilayers graphene coated copper against atomic oxygen irradiation
Zhang, Haijing; Ren, Siming; Pu, Jibin; Xue, Qunji
2018
Source PublicationAPPLIED SURFACE SCIENCE
Volume444Pages:28-35
AbstractGraphene has been demonstrated as a protective coating for Cu under ambient condition because of its high impermeability and light-weight oxidation barrier. However, it lacks the research of graphene as a protective coating in space environment. Here, we experimentally and theoretically study the oxidation behavior of graphene-coated Cu in vacuum atomic oxygen (AO) condition. After AO irradiation, the experimental results show multilayer graphene has better anti-oxidation than monolayer graphene. Meanwhile, the calculation results show the oxidation appeared on the graphene's grain boundaries or the film's vacancy defects for the monolayer graphene coated Cu foil. Moreover, the calculation results show the oxidation process proceeds slowly in multilayers because of the matched defects overlaps each other to form a steric hindrance to suppress the O atom diffusion in the vertical direction, and the mismatched defects generates potential energy barriers for interlayer to suppress the O atom diffusion in the horizontal direction. Hence, multilayer graphene films could serve as protection coatings to prevent diffusion of O atom. (C) 2018 Elsevier B.V. All rights reserved.
KeywordLow-earth-orbit Chemical-vapor-deposition High-quality Space Films Coatings Supercapacitors Temperature Oxidation Corrosion
Subject AreaScience & Technology - Other Topics ; Materials Science
Language英语
Document Type期刊论文
Identifierhttp://ir.nimte.ac.cn/handle/174433/17370
Collection2018专题
Recommended Citation
GB/T 7714
Zhang, Haijing,Ren, Siming,Pu, Jibin,et al. Barrier mechanism of multilayers graphene coated copper against atomic oxygen irradiation[J]. APPLIED SURFACE SCIENCE,2018,444:28-35.
APA Zhang, Haijing,Ren, Siming,Pu, Jibin,&Xue, Qunji.(2018).Barrier mechanism of multilayers graphene coated copper against atomic oxygen irradiation.APPLIED SURFACE SCIENCE,444,28-35.
MLA Zhang, Haijing,et al."Barrier mechanism of multilayers graphene coated copper against atomic oxygen irradiation".APPLIED SURFACE SCIENCE 444(2018):28-35.
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