NIMTE OpenIR  > 2018专题
From Furan to High Quality Bio-based Poly(ethylene furandicarboxylate)
Wang, Jing-Gang; Liu, Xiao-Qing; Zhu, Jin
2018
Source PublicationCHINESE JOURNAL OF POLYMER SCIENCE
Volume36Issue:6Pages:720-727
Abstract2,5-Furandicarboxylic acid (2,5-FDCA) has been regarded as the ideal bio-based alternative to terephthalic acid (TPA). In recent years, great efforts have been made to synthesize 2,5-FDCA through the following methods: (1) oxidation of 5-hydroxymethylfurfural (HMF) in the presence of complex biocatalyst or metallic catalyst; (2) conversion of 2-furoic acid via the well-known Henkel Reaction. Herein, a new strategy for the synthesis of 2,5-FDCA from furan and acetic anhydride under mild condition is reported. The purity of the resulted 2,5-FDCA was above 99.9%. Acetic acid and iodoform generated in the reaction were recyclable and no other harmful by-products were detected. The thus-obtained 2,5-FDCA was applied for the preparation of poly(ethylene furandicarboxylate) (PEF) of high quality in terms of high molecular weight and good appearance.
Keyword2 Catalytic Conversion 5-furandicarboxylic Acid Furan-2 Aerobic Oxidation 5-dicarboxylic Acid Carbon Biomass Hmf Polyester 2 Acylation 5-diformylfuran
Subject AreaChemistry ; Electrochemistry ; Energy & Fuels ; Materials Science
Language英语
Document Type期刊论文
Identifierhttp://ir.nimte.ac.cn/handle/174433/17470
Collection2018专题
Recommended Citation
GB/T 7714
Wang, Jing-Gang,Liu, Xiao-Qing,Zhu, Jin. From Furan to High Quality Bio-based Poly(ethylene furandicarboxylate)[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2018,36(6):720-727.
APA Wang, Jing-Gang,Liu, Xiao-Qing,&Zhu, Jin.(2018).From Furan to High Quality Bio-based Poly(ethylene furandicarboxylate).CHINESE JOURNAL OF POLYMER SCIENCE,36(6),720-727.
MLA Wang, Jing-Gang,et al."From Furan to High Quality Bio-based Poly(ethylene furandicarboxylate)".CHINESE JOURNAL OF POLYMER SCIENCE 36.6(2018):720-727.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Wang, Jing-Gang]'s Articles
[Liu, Xiao-Qing]'s Articles
[Zhu, Jin]'s Articles
Baidu academic
Similar articles in Baidu academic
[Wang, Jing-Gang]'s Articles
[Liu, Xiao-Qing]'s Articles
[Zhu, Jin]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Wang, Jing-Gang]'s Articles
[Liu, Xiao-Qing]'s Articles
[Zhu, Jin]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.