NIMTE OpenIR  > 2018专题
From Furan to High Quality Bio-based Poly(ethylene furandicarboxylate)
Wang, Jing-Gang; Liu, Xiao-Qing; Zhu, Jin
2018
发表期刊CHINESE JOURNAL OF POLYMER SCIENCE
卷号36期号:6页码:720-727
摘要2,5-Furandicarboxylic acid (2,5-FDCA) has been regarded as the ideal bio-based alternative to terephthalic acid (TPA). In recent years, great efforts have been made to synthesize 2,5-FDCA through the following methods: (1) oxidation of 5-hydroxymethylfurfural (HMF) in the presence of complex biocatalyst or metallic catalyst; (2) conversion of 2-furoic acid via the well-known Henkel Reaction. Herein, a new strategy for the synthesis of 2,5-FDCA from furan and acetic anhydride under mild condition is reported. The purity of the resulted 2,5-FDCA was above 99.9%. Acetic acid and iodoform generated in the reaction were recyclable and no other harmful by-products were detected. The thus-obtained 2,5-FDCA was applied for the preparation of poly(ethylene furandicarboxylate) (PEF) of high quality in terms of high molecular weight and good appearance.
关键词2 Catalytic Conversion 5-furandicarboxylic Acid Furan-2 Aerobic Oxidation 5-dicarboxylic Acid Carbon Biomass Hmf Polyester 2 Acylation 5-diformylfuran
学科领域Chemistry ; Electrochemistry ; Energy & Fuels ; Materials Science
语种英语
文献类型期刊论文
条目标识符http://ir.nimte.ac.cn/handle/174433/17470
专题2018专题
推荐引用方式
GB/T 7714
Wang, Jing-Gang,Liu, Xiao-Qing,Zhu, Jin. From Furan to High Quality Bio-based Poly(ethylene furandicarboxylate)[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2018,36(6):720-727.
APA Wang, Jing-Gang,Liu, Xiao-Qing,&Zhu, Jin.(2018).From Furan to High Quality Bio-based Poly(ethylene furandicarboxylate).CHINESE JOURNAL OF POLYMER SCIENCE,36(6),720-727.
MLA Wang, Jing-Gang,et al."From Furan to High Quality Bio-based Poly(ethylene furandicarboxylate)".CHINESE JOURNAL OF POLYMER SCIENCE 36.6(2018):720-727.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Wang, Jing-Gang]的文章
[Liu, Xiao-Qing]的文章
[Zhu, Jin]的文章
百度学术
百度学术中相似的文章
[Wang, Jing-Gang]的文章
[Liu, Xiao-Qing]的文章
[Zhu, Jin]的文章
必应学术
必应学术中相似的文章
[Wang, Jing-Gang]的文章
[Liu, Xiao-Qing]的文章
[Zhu, Jin]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。